1245741-89-2Relevant academic research and scientific papers
Gold-catalyzed intramolecular aminoarylation of alkenes: C-C bond formation through bimolecular reductive elimination
Brenzovich Jr., William E.,Benitez, Diego,Lackner, Aaron D.,Shunatona, Hunter P.,Tkatchouk, Ekaterina,Goddard III, William A.,Toste, F. Dean
supporting information; experimental part, p. 5519 - 5522 (2010/09/05)
(Chemical equation presented) Gold-ilocks and the 3 mol% catalyst: Bimetallic gold bromides allow the room temperature aminoarylation of unactivated terminal olefins with aryl boronic acids using Selectfluor as an oxidant. A catalytic cycle involving gold (I)/gold(III) and a bimolecular reductive elimination for the key C-C bond-forming step is proposed, dppm= bis(diphenylphosphanyl) methane.
