1245917-30-9

Basic information

• Product Name: C₁₅H₉Br₂NO₂
• Synonyms: C₁₅H₉Br₂NO₂
• CAS NO: 1245917-30-9
• Molecular Weight: 395.05
• Mol File: 1245917-30-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₉Br₂NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₉Br₂NO₂(1245917-30-9)
• EPA Substance Registry System: C₁₅H₉Br₂NO₂(1245917-30-9)

Safety Data

• Hazardous Substances Data: 1245917-30-9(Hazardous Substances Data)

Upstream product

• 187326-67-6 4,6-dibromoindoline-2,3-dione 
• 100-39-0 benzyl bromide 

Downstream Products

• 1245917-32-1 C₁₈H₁₅Br₂NO₃ 
• 1266333-62-3 C₂₁H₂₁Br₂NO₃S 

Relevant articles and documents

Palladium-catalyzed enantioselective ene and aldol reactions with isatins, keto esters, and diketones: Reliable approach to chiral tertiary alcohols

Chiral dicationic Pd-complex-catalyzed enantioselective ene and aldol reactions with various isatin derivatives are shown to produce the corresponding 3-hydroxy-2-oxindole products in good yields with high enantioselectivities. These catalytic processes are effective not only with isatins but also with keto esters and diketones derivatives. Even with unprotected isatin, high yields and enantioselectivities were obtained to produce convolutamydine A as a naturally occurring compound. Sequentially, α-oxidation by m-CPBA and α-fluorination by selectfluor of the ene product could be achieved to give the corresponding α-hydroxy and α-fluoro ketones, respectively. Chiral dicationic Pd complex catalyzed enantioselective ene and aldol reactions with various isatin derivatives gave the corresponding 3-hydroxy-2-oxindole products bearing tertiary alcohols in high yields and enantioselectivities.