1246014-24-3Relevant academic research and scientific papers
Synthesis of dihydroindenofuran scaffold via a Pd-catalyzed 5-endo-trig cyclization/enolate O-alkylation cascade
Kim, Eun Sun,Kim, Ko Hoon,Park, Sunhong,Kim, Jae Nyoung
experimental part, p. 4648 - 4652 (2010/10/21)
An efficient synthesis of dihydroindenofurans was carried out starting from the Baylis-Hillman adducts via a Pd-catalyzed 5-endo-trig-carbopalladation and enolate O-alkylation cascade as a key step. This is the first example of enolate O-alkylation with a C(sp3)-bound palladium intermediate.
