124615-73-2Relevant academic research and scientific papers
Phenylselenofluorination of alkenes and alkynes promoted by difluoroiodotoluene and diphenyldiselenide
Panunzi, Barbara,Picardi, Andrea,Tingoli, Marco
, p. 2339 - 2342 (2007/10/03)
The oxidation of diphenyldiselenide with 4-iodotoluene difluoride (DFIT) in dichloromethane produces in situ an efficient phenylselenofluorinating agent of alkenes and internal alkynes.
Fluorination of olefins with PhSeF3, PhSeF5 and PhTeF5
Lermontov, Sergei A.,Zavorin, Sergei I.,Bakhtin, Ilya V.,Pushin, Alexei N.,Zefirov, Nikolai S.,Stang, Peter J.
, p. 75 - 83 (2007/10/03)
Phenyselenium trifluoride, PhSeF3 (PSTF) either oxidatively difluorinates or selenofluorinates olefins, depending on their structures. The pentafluorides PhSeF5 and PhTeF5 appear to be effective difluorinating reagents, af
Electrochemical Fluoro-Chalcogenation
Uneyama, Kenji,Asai, Hideki,Dan-Oh, Yasufumi,Funatsuki, Hiroshi
, p. 395 - 396 (2007/10/03)
Electrochemical fluoro-chalcogenation (S, Se) of alkenes and alkynes, and recycle use of in situ generated PhSeF for allylic fluorination are discussed.
Phenylthio (and phenylseleno)fluorination of alkenes and alkynes using N-phenylthio (and phenylseleno)phthalimide combined with pyridine*9HF or Et3N*3HF complexes
Saluzzo, Christine,Spina, Anna-Maria La,Picq, Dominique,Alvernhe, Gerard,Anker, Daniel,et al.
, p. 831 - 843 (2007/10/02)
N-Phenylthiophthalimide and N-phenylselenophthalimide combined with pyridine*9HF or Et3N*3HF complexes allow the formal addition of elements of PHSF or PhSeF across the carbon-carbon double or triple bond by a one-pot reaction.Pyridine*9HF, a strongly aci
A new synthesis of 2-fluoro-1-olefins
McCarthy, James R.,Matthews, Donald P.,Barney, Charlotte L.
, p. 973 - 976 (2007/10/02)
The first examples of the addition of PhSeF to olefins to yield β-fluoro phenylselenides (2) are reported. β-Fluoro phenylselenides (2) obtained from terminal olefins were converted to the title vinyl fluorides 3 on treatment with ozone, whereas, 2 obtain
BENZENESELENENYL FLUORIDE EQUIVALENT IN SITU GENERATED WITH XeF2-(PhSe)2 IN CH2Cl2 FOR FLUOROSELENENYLATION OF OLEFINS
Uneyama, Kenji,Kanai, Masatomi
, p. 3583 - 3586 (2007/10/02)
Benzeneselenenyl fluoride equivalent has been generated by the reaction of diphenyl diselenide with xenon difluoride in CH2Cl2 at -20 deg C employed for fluoroselenenylation of olefins.
PHENYLSELENOFLUORATION D'ALCENES ACIDO-SENSIBLES
Saluzzo, Christine,Alvernhe, Gerard,Anker, Daniel,Haufe, Guenter
, p. 663 - 666 (2007/10/02)
β-phenylselenofluorides have been synthesized by reaction of olefins (even acido-sensitive ones) with N-phenylselenophthalimide in the presence of triethylamine tris-hydrofluoride.Owing to the regioselectivity observed, this reaction constitutes a good me
Fluoroselenylation of Alkenes
Tomoda, Shuji,Usuki, Yoshinosuke
, p. 1235 - 1236 (2007/10/02)
Treatment of alkenes with the reagent generated by the reaction of silver(I) fluoride with benzeneselenyl bromide under ultrasound irradiation afforded 2-fluoroalkyl selenides in decent yields.
