124615-82-3Relevant academic research and scientific papers
Activation of Sn-Se bond: Regioselective ring opening reaction of epoxides with tributylstannyl phenylselenolate in the presence of a Lewis acid
Nishiyama, Yutaka,Ohashi, Hironori,Itoh, Kazuyoshi,Sonoda, Noboru
, p. 159 - 160 (1998)
When tributylstannyl phenylselenolate (Bu3SnSePh) was allowed to react with epoxides in the presence of BF3·OEt2 as a Lewis acid, the ring opening reaction of epoxides proceeded with complete regioselectivity to afford the
PHENYLSELENENYL CHLORIDE IN ACETONITRILE-WATER; A HIGHLY CONVENIENT REAGENT FOR HYDROXYSELENATION OF OLEFINS AND PREPARATION OF CYCLIC ETHERS FROM DIENES
Toshimitsu, Akio,Aoai, Toshiaki,Owada, Hiroto,Uemura, Sakae,Okano, Masaya
, p. 5301 - 5306 (2007/10/02)
The reaction of phenylselenenyl chloride with olefins in aqueous acetonitrile affords β-hydroxyalkyl phenyl selenides in excellent yields, providing the most convenient method for hydroxyselenation of olefins so far reported.When the reaction was applied to conjugated dienes, monohydroxyselenated products were obtained in good to excellent yields.From non-conjugated dienes, on the other hand, cyclic ethers containing two phenylseleno groups were produced in good to excellent yields, the first step of this reaction being the hydroxyselenation of one double bond.
Highly Convenient Method for Hydroxyselenation of Olefins
Toshimitsu, Akio,Aoai, Toshiaki,Owada, Hiroto,Uemura, Sakae,Okano, Masaya
, p. 412 - 413 (2007/10/02)
Reaction of phenylselenenyl chloride with olefins in aqueous acetonitrile affords β-hydroxyselenides (2) in excellent yields, providing a most convenient method for the hydroxyselenation of olefins.
