Activation of Sn-Se bond: Regioselective ring opening reaction of epoxides with tributylstannyl phenylselenolate in the presence of a Lewis acid

DOI: 10.1246/cl.1998.159

Source and publish data:

Chemistry Letters p. 159 - 160 (1998)

Update date:2022-08-11

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Authors:

Nishiyama, Yutaka

Ohashi, Hironori

Itoh, Kazuyoshi

Sonoda, Noboru

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Article abstract of DOI:10.1246/cl.1998.159

When tributylstannyl phenylselenolate (Bu₃SnSePh) was allowed to react with epoxides in the presence of BF₃·OEt² as a Lewis acid, the ring opening reaction of epoxides proceeded with complete regioselectivity to afford the

Full text of DOI:10.1246/cl.1998.159

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