1246167-89-4Relevant academic research and scientific papers
A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation
Bebbington, Magnus W.P.,Bontemps, Sebastien,Bouhadir, Ghenwa,Hanton, Martin J.,Tooze, Robert P.,Van Rensburg, Hendrick,Bourissou, Didier
, p. 1556 - 1559 (2010)
The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.
Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2
Tlili, Anis,Voituriez, Arnaud,Marinetti, Angela,Thuéry, Pierre,Cantat, Thibault
supporting information, p. 7553 - 7555 (2016/07/06)
The benefit of combining both a Lewis acid and a Lewis base in a catalytic system has been established for the hydroboration of CO2, using ferrocene-based phosphine, borane and phosphino-borane derivatives.
