1246261-65-3Relevant articles and documents
Stable, glassy, and versatile binaphthalene derivatives capable of efficient hole transport, hosting, and deep-blue light emission
Wei, Bin,Liu, Ji-Zhong,Zhang, Yong,Zhang, Jian-Hua,Peng, Hua-Nan,Fan, He-Liang,He, Yan-Bo,Gao, Xi-Cun
, p. 2448 - 2458 (2011/11/30)
Organic light-emitting diodes (OLEDs) have great potential applications in display and solid-state lighting. Stability, cost, and blue emission are key issues governing the future of OLEDs. The synthesis and photoelectronics of a series of three kinds of binaphthyl (BN) derivatives are reported. BN 1-3 are "melting-point-less" and highly stable materials, forming very good, amorphous, glass-like films. They decompose at temperatures as high as 485-545 °C. At a constant current density of 25 mA cm -2, an ITO/BN3/Al single-layer device has a much-longer lifetime (>80 h) than that of an ITO/NPB/Al single-layer device (8 h). Also, the lifetime of a multilayer device based on BN1 is longer than a similar device based on NPB. BNs are efficient and versatile OLED materials: they can be used as a hole-transport layer (HTL), a host, and a deep-blue-light-emitting material. This versatility may cut the cost of large-scale material manufacture. More importantly, the deep-blue electroluminescence (emission peak at 444 nm with CIE coordinates (0.16, 0.11), 3.23 cd A-1 at 0.21 mA cm-2, and 25200cd m-2 at 9V) remains very stable at very high current densities up to 1000 mA cm -2.