124648-75-5Relevant academic research and scientific papers
PREPARATION OF NEW DINITROGEN COMPLEXES OF RHENIUM(I) WITH ORGANOPHOSPHITE AND ISOCYANIDE LIGANDS. X-RAY STRUCTURE OF mer-3>
Carvalho, Fernanda N. N.,Pombeiro, Armando J. L.,Orama, Olli,Schubert, Ulrich,Pickett, Christopher J.,Richards, Raymond L.
, p. C18 - C22 (2007/10/02)
The mixed dinitrogen-isocyanide complexes mer-3> (I) and 2> (II) are obtained by a novel route through reactions of CNMe with the organodiazenido species 3> and 2> (III, newly synthesized), whereas mer-3> (IV) (which gives I by reaction with CNMe) is formed in the reaction of with P(OMe)3; the structure of complex I is authenticated by X-ray analysis.
