1246560-84-8Relevant academic research and scientific papers
A ditetrylyne as a π-electron donor: Synthesis and characterization of [AgAr′GeGeAr′]+SbF6- and [Ag 2Ar′GeGe(F)Ar′]+SbF6- (Ar′ = C6H3-2,6(C6H3-2,6- Pri2)2)
Wang, Xinping,Peng, Yang,Olmstead, Marilyn M.,Hope, Haakon,Power, Philip P.
, p. 13150 - 13151 (2010)
The reaction of a digermyne Ar′GeGeAr′ (Ar′ = C 6H3-2,6-(C6H3-2,6-Pr i2)2) with AgSbF6 at-40 °C forms the complex (AgAr′GeGeAr′)+SbF6-, which provides the first example of a heavier group 14 element alkyne analogue behaving as a π donor to a transition metal. The cation (AgAr′ GeGeAr′)+ is best described as a hybrid of a π-complex and a σ-metallacyclopropene structure.
