1246678-22-7Relevant academic research and scientific papers
1-Azido-1-Alkynes: Synthesis and spectroscopic characterization of azidoacetylene
Banert, Klaus,Arnold, Rene,Hagedorn, Manfred,Thoss, Philipp,Auer, Alexander A.
supporting information; experimental part, p. 7515 - 7518 (2012/09/10)
Sleeping Beauty awakes: After 102 years of unsuccessful attempts to synthesize azidoacetylene, spectroscopic evidence for this compound has been shown. This highly explosive compound was synthesized by the treatment of ethynyliodonium salts with azide (QN3=n-C16H 33Bu3PN3). Azidoacetylene can be trapped by a cycloaddition reaction to yield a stable triazole, otherwise cleavage to generate cyanocarbene dominates. Copyright
Elusive ethynyl azides: Trapping by 1,3-dipolar cycloaddition and decomposition to cyanocarbenes
Banert, Klaus,Hagedorn, Manfred,Wutke, Jens,Ecorchard, Petra,Schaarschmidt, Dieter,Lang, Heinrich
supporting information; experimental part, p. 4058 - 4060 (2010/09/06)
Although they decompose rapidly to produce cyanocarbenes, ethynyl azides were generated from (chloroethynyl)arenes and trapped for the first time by 1,3-dipolar cycloaddition at cyclooctyne.
