1246762-58-2Relevant academic research and scientific papers
NMR (1D and 2D) and X-ray crystallographic studies of Ni(II) complex with N-(2-mercaptophenyl)-4-methoxysalicylideneimine and triphenylphosphine
Muthu Tamizh,Varghese,Endo,Karvembu
, p. 411 - 418 (2010)
Mononuclear nickel(II) complex, viz. [Ni(L)(PPh3)] (where L is dianion of N-(2-mercaptophenyl)-4-methoxysalicylideneimine) has been synthesized and characterized by means of elemental analysis, electronic, IR and NMR [ 1H, 13C{1H} and 31P{1H}, DEPT, 1H-1H COSY, ge-HSQC, ge-HMBC] spectroscopic techniques. Structural analysis of the complex by single crystal X-ray crystallography indicated the presence of square planar coordination geometry (ONSP) about nickel. One of the phenyl rings of triphenylphosphine involve in CH...π interactions with H6b, H13 and H32 to form a three dimensional network which stabilizes the structure of complex.
