1246768-82-0

Upstream product

• 1309666-38-3 (N-anisoyl)benzimidazol-2-yl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside 
• 105376-04-3 ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside 
• 14218-11-2 2,3,4,6-tetra-O-benzoylglucosyl bromide 
• 42975-31-5 2-benzimidazolethione potassium salt 
• 583-39-1 2,3-dihydrobenzimidazol-2-thione 

Downstream Products

• 128503-39-9 methyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl)-α-D-glucopyranoside 
• 118579-76-3 methyl 4-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 1309666-38-3 (N-anisoyl)benzimidazol-2-yl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

Revisit to the reaction of o-phenylene diamine with thiosemicarbazide to give benzimidazole-2-thione rather than benzotriazine-2-thione and its glycosylation

Reaction of o-phenylene diamine with thiosemicarbazide did not give benzotriazine-2-thione 2 as reported, although the product was found to be benzimidazole-2-thione 3. Glycosylation of 3 with acetobromo sugars 4α-4b gave the respective thioglycosides 7α-7d in addition to minor products of the nucleosides 8α and 8b, in the case of the gluco-and galacto-analogs, respectively. The regioselectivity of glycosylation reaction has been investigated. Taylor and Francis Group, LLC.

S-benzimidazolyl glycosides as a platform for oligosaccharide synthesis by an active-latent strategy

Doing the Biz: The S-benzimidazolyl (SBiz) anomeric moiety is a new leaving group that can be activated for glycosylation under a variety of conditions, including metal-assisted and alkylation pathways. Application of a substituted SBiz moiety (X=anisoyl, see picture) allows active-latent and armed-disarmed types of oligosaccharide assembly. Copyright