14218-11-2

Basic information

• Product Name: 2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
• Synonyms: 2,3,4,6-TETRA-O-BENZOYL-A-D-GLUCOPYRANOSYL BROMIDE;2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE;1-BROMO-2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSE;ALPHA-D-GLUCOPYRANOSYL BROMIDE TETRABENZOATE;1-BROMO-2,3,4,6-TETRA-O-BENZOYL-B-D-GLUCOPYRANOSIDE;α-d-glucopyranosyl bromide tetrabenzoate;(2R,3R,4S,5R,6R)-2-((Benzoyloxy)Methyl)-6-broMotetrahydro-2H-pyran-3,4,5-triyl tribenzoate
• CAS NO: 14218-11-2
• Molecular Formula: C₃₄H₂₇BrO₉
• Molecular Weight: 659.48
• Product Categories: Carbohydrate Synthesis;Monosaccharides;Specialty Synthesis
• Mol File: 14218-11-2.mol
• Article Data: 54

Chemical Properties

• Melting Point: 128-131 °C(lit.)
• Boiling Point: 729.919 °C at 760 mmHg
• Flash Point: 395.241 °C
• Appearance: /
• Density: 1.48 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.648
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility: Chloroform (Slightly), DMSO (Slightly)
• Stability: Hygroscopic
• CAS DataBase Reference: 2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE(14218-11-2)
• EPA Substance Registry System: 2,3,4,6-TETRA-O-BENZOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE(14218-11-2)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 14218-11-2(Hazardous Substances Data)

Usage

Chemical Properties

White to off-white powder

Uses

2,3,4,5-Tetra-O-benzoyl-α-D-glucopyranosyl bromide (CAS# 14218-11-2) is a useful carbohydrate used in the synthesis of steviol glycosides, and glycosyl polyethers.

InChI:InChI=1/C34H27BrO9/c35-30-29(44-34(39)25-19-11-4-12-20-25)28(43-33(38)24-17-9-3-10-18-24)27(42-32(37)23-15-7-2-8-16-23)26(41-30)21-40-31(36)22-13-5-1-6-14-22/h1-20,26-30H,21H2/t26-,27-,28+,29-,30+/m1/s1

Upstream product

• 2592-58-7 1,2,3,4,6-penta-O-benzoyl-α-D-mannopyranoside 
• 3458-28-4 D-Mannose 
• 618-32-6 Benzoyl bromide 
• 2592-58-7 1,2,3,4,6-penta-O-benzoyl-D-glucopyranoside 
• 183367-63-7 1-p-methylphenyltelluro-2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 50-99-7 D-glucose 
• 492-61-5 β-D-glucose 
• 69534-63-0 1,2,3,4,6-penta-O-benzoyl-5-C-bromo-β-D-glucopyranose 
• 245368-66-5 ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-α-D-glucopyranoside 
• 409060-31-7 p-methoxyphenyl (2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 627466-64-2 2,3,4,6-tetra-O-benzoyl-D-glucopyranose 
• 108-93-0 cyclohexanol 
• 22415-91-4 1,2,3,4,6-penta-O-benzoyl-α-D-glucopyranose 

Downstream Products

• 129941-07-7 methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 129870-10-6 methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 123487-55-8 3,4,6-tri-O-benzoyl-β-D-mannopyranose 1,2-(pent-4-enyl orthobenzoate) 
• 152501-52-5 octyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranoside 
• 121768-02-3 ethyl 4,8-anhydro-5,6,7,9-tetra-O-benzoyl-2,3-dideoxy-2-C-ethoxycarbonyl-D-glycero-D-talonononate 
• 152501-53-6 tetradecyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranoside 
• 77666-97-8 8-(methoxycarbonyl)octyl α-D-mannoipyranoside 
• 158975-47-4 N-(carbobenzoxy)-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-(1<*>3)-L-serine methyl ester 
• 132150-15-3 C₄₇H₄₆O₁₁ 
• 129440-28-4 6-(N-Acryloylamino)hexyl 2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranoside 
• 135195-72-1 methyl onate 
• 136737-29-6 benzyl 3-O-benzyl-2-deoxy-4-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-β-L-erythro-pentopyranoside 
• 137438-90-5 Methyl 2-O-acetyl-4-O-benzyl-3-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-α-L-rhamnopyranoside 
• 123487-61-6 pent-4-enyl 2-O-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 

Relevant articles and documents

Nickel-Catalyzed Radical Migratory Coupling Enables C-2 Arylation of Carbohydrates

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