1246858-48-9Relevant academic research and scientific papers
Lipase-catalyzed kinetic resolution of α-hydroxymethylcycloalkanones with a quaternary carbon center. Chemoenzymatic synthesis of chiral pseudoiridolactones
Guerrab, Zineb,Schweiger, Stefan,Daou, Boujemaa,Ahmar, Mohammed,Cazes, Bernard
experimental part, p. 1752 - 1757 (2010/10/21)
The resolution of α-alkyl-α-hydroxymethylcyclopentanones 1 and cyclohexanones 3 has been efficiently achieved by using lipase-catalyzed transesterification reactions with vinyl acetate as the acylating agent. The enantiomeric selectivities were dependent
PROCESS FOR PRODUCTION OF OPTICALLY ACTIVE HYDROXYMETHYLATED COMPOUNDS
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Page/Page column 6, (2010/11/24)
The present invention presents a catalyst that allows asymmetric hydroxymethylation reactions to progress with excellent asymmetric selectivity and a production method for optically active hydroxymethylated compounds using the catalyst. Optically active h
PROCESS FOR PRODUCTION OF OPTICALLY ACTIVE HYDROXYMETHYLATED COMPOUNDS AND CATALYST THEREFOR
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Page/Page column 12-13, (2008/06/13)
[PROBLEMS] To provide a process for producing optically active hydroxymethylated compounds in high yields at high stereoselectivity with broad substrate generality, and a catalyst for the production. [MEANS FOR SOLVING PROBLEMS] The process comprises reac
