1247025-83-7Relevant academic research and scientific papers
Unique fluorescence of boronic acid derived salicylidenehydrazone complexes with two perpendicular ICT: Solvent effect on PET process
Zhang, Boyu,Wang, Shichao,Tan, Jingyun,Zhang, Xuanjun
, p. 186 - 193 (2018)
Solvent effects on the absorption and emission spectra of organic compounds have been widely observed. It is usually found that the positions, intensities and shapes of its bands are usually modified by these solvents. The solvent effects on intramolecula
Boronic acid derived salicylidenehydrazone complexes for wash-free fluorescence imaging of cellular organelles
Zhang, Boyu,Feng, Gang,Wang, Shichao,Zhang, Xuanjun
, p. 356 - 362 (2018)
Wash-free fluorescence imaging process has intrinsic nature of monitoring biochemical process in real time fashion and enable us to get more insight on living organism. In this contribution, it was proved that boronic acid derived salicylidenehydrazone complexes (BSs) are suitable candidates for wash-free fluorescence labels. Through pre-installation of organelles' targeting group morpholine and triphenylphosphonium (TPP+) on phenyboronic acid and then assembly it with salicylidenehydrazone ligand by dehydration and dative N-B bond, Lyso-BS and Mito-BS were acquired, which were shown to selectively stain lysosomes and mitochondria with circumventing tedious wash-off procedures in Hela cells respectively, without inducing any appreciable cytotoxicity. Our findings indicate that BSs are potential candidates as wash-free fluorescent stains.
Real-Time Mass Spectrometric Investigations into the Mechanism of the Suzuki-Miyaura Reaction
Yunker, Lars P. E.,Ahmadi, Zohrab,Logan, Jessamyn R.,Wu, Wenzhao,Li, Tengfei,Martindale,Oliver, Allen G.,McIndoe, J. Scott
, p. 4297 - 4308 (2018)
Real-time monitoring of the Suzuki-Miyaura reaction using mass spectrometry during sequential addition of the various reaction components suggests that a dynamic series of equilibria exist in these solutions. Depending on conditions, the boronic acid can
Boronated phosphonium salts containing arylboronic acid, closo-carborane, or nido-carborane: Synthesis, X-ray diffraction, in vitro cytotoxicity, and cellular uptake
Morrison, Daniel E.,Issa, Fatiah,Bhadbhade, Mohan,Groebler, Ludwig,Witting, Paul K.,Kassiou, Michael,Rutledge, Peter J.,Rendina, Louis M.
experimental part, p. 1305 - 1318 (2011/10/02)
The preparation of boronated triaryl and tetraaryl phosphonium salts of the type [PPh3CH2R]Br [R is 4-boronophenyl (1), 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-yl)phenyl (2), 3-boronophenyl (3), 3-(4,4,5,5-tetramethyl-1,3,2-dioxabo
