124755-32-4

Upstream product

• 124755-31-3 (2S,3S,4S,6R)-1,3-(benzylidenedioxy)-7-<(p-methoxybenzyl)oxy>-2,4,6-trimethylheptane 
• 124755-27-7 (E)-(2R,5R,6S)-7-<(tert-butyldimethylsilyl)oxy>-2,4,6-trimethyl-3-heptene-1,5-diol 
• 124755-29-9 (2S,3S,4S,6R)-1,3-(benzylidenedioxy)-2,4,5-trimethyl-heptan-7-ol 
• 124755-28-8 (2S,3R,5R)-1,3-(benzylidenedioxy)-2,4,5-trimethyl-4-hepten-7-ol 
• 124755-30-2 (2R,4S)-4-[(2'R,4'S,5'S)-2'-(4-methoxyphenyl)-5'-methyl-1',3'-dioxan-4-yl]-2-methylpentan-1-ol 

Relevant academic research and scientific papers

Synthesis of Polypropionate Subunits by SN2'Addition of Cuprates to Nonracemic Acyclic Vinyloxiranes

Synthetic sequences have been devised for conversion of the chiral pool ester 1 to differentially protected polypropionate subunit polyols 11, 13, 18, and 20.The following stereochemically significant steps were employed: (1) reagent directed Sharpless ep