124774-78-3Relevant articles and documents
A Weakly Antiferromagnetically Coupled Biradical Combining Verdazyl with Nitronylnitroxide Units
Petunin, Pavel V.,Rybalova, Tatyana V.,Trusova, Marina E.,Uvarov, Mikhail N.,Kazantsev, Maxim S.,Mostovich, Evgeny A.,Postulka, Lars,Eibisch, Paul,Wolf, Bernd,Lang, Michael,Postnikov, Pavel S.,Baumgarten, Martin
, p. 159 - 162 (2020/01/25)
An antiferromagnetically (AFM) coupled biradical based on oxoverdazyl and nitronylnitroxide was synthesized in 46 % yield using Sonogashira coupling. The obtained heterobiradical evidenced distinct properties of both radical entities in solution. Dependin
Spin exchange interaction through phenylene-ethynylene bridge in diradicals based on iminonitroxide and nitronylnitroxide radical derivatives. 1. Experimental investigation of the through-bond spin exchange coupling
Wautelet, Pascale,Le Moigne, Jacques,Videva, Vladimira,Turek, Philippe
, p. 8025 - 8036 (2007/10/03)
A series of bis-iminonitroxide diradical derivatives of different lengths and geometry have been prepared that incorporate a conjugated phenylene-ethynylene bridge as a rigid spacer. This paper describes the synthesis of these new components and their main characterizations. An unexpected singlet ground state and substituent effects on the singlet-triplet gap have been found for substituted "m-phenylene"-based diradicals. The effects of the π-conjugation on the intramolecular through-bond spin coupling have been investigated by changing the length of the spacer within linear derivatives. The EPR studies demonstrate the intramolecular magnetic coupling between the radical spins within all compounds. This result is very attractive and unusual, given the large distance between the radicals from 15 A in the dimer to 36 A in the pentamer.
Synthesis of nitronyl- and imino-nitroxide-triradicals interconnected by phenyl ethynyl spacer
Catala, Laure,Turek, Philippe,Le Moigne, Jacques,De Cian, André,Kyritsakas, Nathalie
, p. 1015 - 1018 (2007/10/03)
The design and synthesis, as well as solid state and ESR characterisation of three new triradicals based on phenyl ethynyl backbone bearing nitronyl-nitroxide and imino-nitroxide groups, are reported. The synthesis of these compounds was based on palladium-coupling reactions between alkynyl and bromo derivatives. An ESR study showed magnetic interactions between the radicals through the phenyl ethynyl-coupling unit in solution. (C) 2000 Elsevier Science Ltd.