124872-82-8Relevant academic research and scientific papers
Synthesis of the Benzodioxane Portion of Haedoxans
Ishibashi, Fumito,Taniguchi, Eiji
, p. 1557 - 1564 (2007/10/02)
(2R*,3R*)-6-Formyl-7-methoxy-3-methoxymethyl-2-(3',4'-methylenedioxyphenyl)-2,3-dihydro-1,4-benzodioxine, a starting material for haedoxan synthesis, was synthesized from 2,4-dihydroxybenzaldehyde.
Structure of the Novel Insecticidal Sesquilignan, Haedoxan A
Taniguchi, Eiji,Imamura, Keiichi,Ishabashi, Fumito,Matsui, Toshio,Nishio, Akira
, p. 631 - 644 (2007/10/02)
Haedoxan A, a new insecticidal sesquilignan, was isolated from the root of Hae-doku-sou, Phyrma leptostachya L., and the structure was elucidated as 1-hydroxy-2--6--3,7-dioxabicyclooctane on the basis of spectroscopic and chemical information involving synthesis of its partial structures.Its relative stereochemistry was revealed to be (1S*, 2R*, 5R*,6S*, 2'R*, 3'R*) or 1S*, 2R*, 5R*, 2'S*, 3'S*).
