124900-91-0Relevant academic research and scientific papers
Reactions of Amine Hydrochlorides with Phosphorus Trichloride Oxide; Preparation and X-Ray Crystal Structure of 2,4,6-Trichloro-1,3,5-triphenyl-1,3,5,2λ54λ5,6λ5-triazatriphosphorinane 2,4,6-trioxide (PhNPOCl)3
Johnson, Owen,Murray, Martin,Woodward, Gary
, p. 821 - 828 (2007/10/02)
The reaction of aniline hydrochloride with POCl3 has been shown to yield trimeric cyclophosphazane (PhNPOCl)3 in good yield and purity, in opposition to the earlier results of Michaelis which assigned a dimeric structure to the product.The trimeric nature
MECHANISMS OF FORMATION OF THE CYCLODIPHOSPHAZANE AND CYCLOTRIPHOSPHAZANE RING SYSTEMS.
Murray, M.,Woodward, G.
, p. 399 - 404 (2007/10/02)
Four- and six-membered phosphorus(V) nitrogen ring compounds have been prepared from phosphorus(V) halides and amides, and their structures determined by n.m.r, mass spectroscopy and X-ray crystallography.The role ot three-coordinated intermediates is discussed.
