124908-64-1

Basic information

• Product Name: 1,1,1-trimethyl-2,2-diphenylchlorodigermane
• Synonyms: 1,1,1-trimethyl-2,2-diphenylchlorodigermane
• CAS NO: 124908-64-1
• Molecular Weight: 379.949
• Mol File: 124908-64-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,1,1-trimethyl-2,2-diphenylchlorodigermane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1-trimethyl-2,2-diphenylchlorodigermane(124908-64-1)
• EPA Substance Registry System: 1,1,1-trimethyl-2,2-diphenylchlorodigermane(124908-64-1)

Safety Data

• Hazardous Substances Data: 124908-64-1(Hazardous Substances Data)

Upstream product

• 1359144-15-2 Ph₂(OTf)Ge₂Me₃ 
• 1048-05-1 tetraphenylgermane 
• 1626-24-0 chlorotriphenylgermane 
• 3839-32-5 triphenyl germyllithium 
• 20213-96-1 1,1,1-trimethyl-2,2,2-triphenyldigermane 
• 53421-59-3 1,1,1,3,3,3-hexamethyl-2,2-diphenyl-trigermane 

Relevant articles and documents

Reaction of germanes and digermanes with triflic acid: The route to novel organooligogermanes

Novel germanium containing triflates were prepared from the reactions of trifluoromethanesulfonic acid with tetraphenylgermane (1) and digermanes (Ph3GeGeMe3 (4), Ph3GeGePh3 (5)). The improved procedures for synthesis of known organogermanium compounds (Ph4Ge (1), Ph3GeCl (2), Ph3GeGeMe3 (4), Ph3GeGePh3 (5)) were also presented. The crystal structure of Ph3GeOTf (6) and Ph2Ge(OTf)Ge(OTf)Ph 2 (7) was studied by X-ray analysis. In 7 each germanium atom is pentacoordinated due to intramolecular interaction with O atom of the neighboring triflate group.

Photochemistry of aryl-substituted trigermanes

The photolysis of phenyl-substituted trigermanes affords digermanes and germenylenes.Trapping experiments, matrix isolation, and laser-photolysis studies indicate that the photoreaction of these compounds involves both the extrusion of germylenes and the