53421-59-3Relevant academic research and scientific papers
Preparation, structural characterization, and reactivities of (digermanyl)lithium. Its application to the synthesis of bis(1,1-dipheny 1-2,2,2-trimethyldigermanyl)platinum(II)
Mochida, Kunio,Ogawa, Satoshi,Naito, Noriaki,El-Al Gaber, Abd,Usui, Yoko,Nanjo, Masato
, p. 414 - 415 (2007/10/03)
(Pentamethyldigermanyl)lithium (Me3GeGeMe2Li, 1a) and (1,1-diphenyl-2,2,2- trimethyldigermanyl)lithium (MeaGeGe-Ph2Li, 1b) were prepared and characterized by spectroscopic methods. The structure of (digermanyl)lithium 1b was established by X-ray diffraction. The reaction of 1b with cis-PtCl 2-(PMe2Ph)2 gave the expected substitution product, transPt(Me3GePh2Ge)2(PMe 2Ph)2. Copyright
Development of novel and efficient synthesis of group 14 element (Ge and Sn) catenates by use of samarium (II) diiodide
Azemi, Takushi,Yokoyama, Yasuo,Mochida, Kunio
, p. 1588 - 1593 (2007/10/03)
Group 14 element catenates such as di-, tri-, poly-germanes, and polystannanes are efficiently synthesized by use of the one-electron reducing agent SmI2 under mild homogeneous conditions in good yields.
The First Application of Samarium(II) Diiodide for the Formation of Group 14 Element Catenates: Synthesis of Tri- or Poly-germanes and Polystannanes
Yokoyama, Yasuo,Hayakawa, Masamichi,Azemi, Takushi,Mochida, Kunio
, p. 2275 - 2276 (2007/10/02)
Some Group 14 element catenates such as tri- or poly-germanes and polystannanes are synthesized by use of the one-electron reducing agent SmI2.
