124908-71-0

Upstream product

• 62089-34-3 3-methoxy-5-methylbenzoic acid 

Downstream Products

• 142560-67-6 (Z)-3-[(1R,2R,3S)-2-((R)-Cyano-methyl-methyl)-3-methyl-cyclohexyl]-2-((2S,3S,6R)-6-{(E)-3-[(2S,5S)-5-((R)-1-methoxy-ethyl)-tetrahydro-furan-2-yl]-propenyl}-3-methyl-tetrahydro-pyran-2-yl)-acrylic acid methyl ester 
• 142459-45-8 (E)-3-[(1R,2R,3S)-2-((R)-Cyano-methyl-methyl)-3-methyl-cyclohexyl]-2-((2S,3S,6R)-6-{(E)-3-[(2S,5S)-5-((R)-1-methoxy-ethyl)-tetrahydro-furan-2-yl]-propenyl}-3-methyl-tetrahydro-pyran-2-yl)-acrylic acid methyl ester 
• 142459-50-5 C₄₁H₆₈O₈Si 
• 142459-48-1 4-Methoxy-3-((R)-2-{(1R,2R,6S)-2-[(E)-2-((2S,3S,6R)-6-{(E)-3-[(2S,5S)-5-((R)-1-methoxy-ethyl)-tetrahydro-furan-2-yl]-propenyl}-3-methyl-tetrahydro-pyran-2-yl)-3-triethylsilanyloxy-propenyl]-6-methyl-cyclohexyl}-propionyl)-5-methylene-5H-furan-2-one 
• 142459-49-2 3-((R)-2-{(1R,2R,6S)-2-[(E)-3-Hydroxy-2-((2S,3S,6R)-6-{(E)-3-[(2S,5S)-5-((R)-1-methoxy-ethyl)-tetrahydro-furan-2-yl]-propenyl}-3-methyl-tetrahydro-pyran-2-yl)-propenyl]-6-methyl-cyclohexyl}-propionyl)-4-methoxy-5-methylene-5H-furan-2-one 
• 142459-47-0 (R)-2-{(1R,2R,6S)-2-[(E)-2-((2S,3S,6R)-6-{(E)-3-[(2S,5S)-5-((R)-1-Methoxy-ethyl)-tetrahydro-furan-2-yl]-propenyl}-3-methyl-tetrahydro-pyran-2-yl)-3-triethylsilanyloxy-propenyl]-6-methyl-cyclohexyl}-propionaldehyde 
• 142459-44-7 3-[(1R,2S,3S)-2-((R)-Cyano-methyl-methyl)-3-methyl-cyclohexyl]-3-hydroxy-2-((2S,3S,6R)-6-{(E)-3-[(2S,5S)-5-((R)-1-methoxy-ethyl)-tetrahydro-furan-2-yl]-propenyl}-3-methyl-tetrahydro-pyran-2-yl)-propionic acid methyl ester 
• 142459-46-9 (R)-2-{(1R,2R,6S)-2-[(E)-3-Hydroxy-2-((2S,3S,6R)-6-{(E)-3-[(2S,5S)-5-((R)-1-methoxy-ethyl)-tetrahydro-furan-2-yl]-propenyl}-3-methyl-tetrahydro-pyran-2-yl)-propenyl]-6-methyl-cyclohexyl}-propionaldehyde 
• 142560-63-2 (4S,5S)-5-<<(tert-Butyldimethylsilyl)oxy>-methyl>-4-<(1R)-1-cyanoethyl>-3-methylcyclohex-2-en-1-one 
• 124908-75-4 (3S,4S,5S)-5-<<(tert-Butyldimethylsilyl)oxy>-methyl>-4-<(1R)-1-cyanoethyl>-3-methylcyclohexan-1-one 
• 124908-76-5 (1S,2S,3S)-1-<<(tert-Butyldimethylsilyl)oxy>-methyl>-2-<(1R)-1-cyanoethyl>-3-methylcyclohexane 
• 142630-58-8 (1R,2S,3S)-1-Formyl-2-<(1R)-1-cyanoethyl>-3-methylcyclohexane 
• 142459-43-6 (1R,2S,3S)-2-<(R)-1-Cyanoethyl>-1-(hydroxymethyl)-3-methylcyclohexane 
• 142459-32-3 (3-Methoxy-5-methyl-cyclohexa-2,5-dienyl)-methanol 

Relevant academic research and scientific papers

Synthesis of the Acyltetronic Acid Fragment of Tetronomycin

Synthesis of the left-hand portion of tetronomycin (1) via an aldol reaction of methyl γ-methylene-β-tetronate (12) with aldehyde (11) prepared from 3-methoxy-5-methylbenzoic acid is reported.