124920-16-7

Basic information

• Product Name: N-(1-methoxybutyl)-4-methylbenzenesulfonamide
• Synonyms: N-(1-methoxybutyl)-4-methylbenzenesulfonamide
• CAS NO: 124920-16-7
• Molecular Weight: 257.354
• Mol File: 124920-16-7.mol

Chemical Properties

• CAS DataBase Reference: N-(1-methoxybutyl)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-methoxybutyl)-4-methylbenzenesulfonamide(124920-16-7)
• EPA Substance Registry System: N-(1-methoxybutyl)-4-methylbenzenesulfonamide(124920-16-7)

Safety Data

• Hazardous Substances Data: 124920-16-7(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1907-65-9 N-butyl-4-toluenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 123-72-8 butyraldehyde 
• 73183-34-3 bis(pinacol)diborane 
• 959865-56-6 (E)-N-butylidene-4-methylbenzenesulfonamide 

Downstream Products

• 109949-96-4 N-(1-Dimethoxymethyl-propyl)-4-methyl-benzenesulfonamide 
• 124920-17-8 4-Methyl-N-(1-propyl-but-3-enyl)-benzenesulfonamide 

Relevant articles and documents

Direct Synthesis of Hemiaminal Ethers via a Three-Component Reaction of Aldehydes, Amines and Alcohols

The reaction of aldehydes, amines and alcohols usually leads to a series of equilibria from which isolation of one product is difficult to achieve. We have found that this three-component reaction can be controlled and directed in an exclusive manner toward the formation of the hemiaminal ether. A series of 33 hemiaminal ethers has been obtained in high yields, from different aldehydes, amines and alcohols, under very mild conditions just with molecular sieves as promoter.

Copper-boryl mediated transfer hydrogenation of N-sulfonyl imines using methanol as the hydrogen donor

B2Pin2-assisted copper-catalyzed transfer hydrogenation of aromatic sulfonylimines has been achieved, delivering a variety of aryl/heteroaryl sulfonamides in good to excellent yields under mild reaction conditions and with methanol a

Electroorganic chemistry. 120. New patterns of anodic oxidation of amides. Synthesis of α-amino aldehyde acetals and pyrrolidines from amines

Anodic oxidation of N-alkyltosylamides 1 in methanol containing KX (X = Br, I) gave two types of products, α-(tosylamino) aldehyde acetals 2 and pyrrolidine derivatives 3, and each of the products could selectively be formed by modifying the reaction conditions when the alkyl group on the nitrogen of 1 was not branched at its α-position. Namely, anodic oxidation ot N-(α-unbranched alkyl)tosylamides 1a-g in methanol containing NaOMe and KI at -10°C followed by further anodic oxidation at 25°C afforded 2 in good yields, while that of 1 in a two-layer system consisting of cyclohexane and water containing KOH and KBr under heating yielded solely 3. On the other hand, N-(α-branched alkyl)tosylamides 1h-j gave always 3. Two types of reaction routes leading to each of the products were proposed.