124941-28-2Relevant academic research and scientific papers
SELECTIVE OXIDATION OF ALCOHOLS BY MANGANATES
Kim, Kwan Soo,Chung, Sangjae,Cho, In Haeng,Hahn, Chi Sun
, p. 2559 - 2562 (1989)
K2MnO4 oxidized allylic and benzylic alcohols but did not affect saturated alcohols under phase-transfer catalysis condition, whereas a solid mixture of BaMnO4, Al2O3, and CuSO4*5H2O selectively oxidized allylic, benzylic, and saturated secondary hydroxy groups to the corresponding carbonyl groups in the presence of saturated primary hydroxy groups.
Stereoselective Synthesis of Highly Substituted Tetrahydrofurans through Diverted Carbene O-H Insertion Reaction
Nicolle, Simon M.,Lewis, William,Hayes, Christopher J.,Moody, Christopher J.
supporting information, p. 8485 - 8489 (2015/11/27)
Copper- or rhodium-catalyzed reactions of diazocarbonyl compounds with β-hydroxyketones give highly substituted tetrahydrofurans with excellent diastereoselectivity. Under mild conditions, the single-step process starts as a carbene O-H insertion reaction, but is diverted by an intramolecular aldol reaction. Gone astray: Copper- or rhodium-catalyzed reactions of diazocarbonyl compounds with β-hydroxyketones give highly substituted tetrahydrofurans with excellent diastereoselectivity. The single-step reaction proceeds under mild conditions, starting as a carbene O-H insertion reaction, but then diverting to an intramolecular aldol reaction.
Selective oxidation of alcohols using benzyldimethyltelluronium dichromate
Song, Yang-Heon
, p. 631 - 635 (2007/10/03)
Selective oxidation of benzylic, allylic, and saturated secondary alcohols to the corresponding aldehydes or ketones by benzyldimethyltelluronium dichromate is described. Copyright Taylor & Francis Group, LLC.
Selective Oxidation of Allylic and Benzylic Alcohols Using Potassium Ruthenate (K2RuO4) Under Phase-Transfer Catalysis Conditions
Kim, Kwan Soo,Kim, Sung Jung,Song, Yang Heon,Hahn, Chi Sun
, p. 1017 - 1018 (2007/10/02)
Catalytic amounts of potassium ruthenate in the presence of potassium peroxodisulfate, which quickly regenerates ruthenate during reaction, selectively oxidize allylic and benzylic alcohols in the presence of Adogen 464 as phase-transfer catalyst at room temperature but do not affect saturated alcohols.
SELECTIVE OXIDATION OF ALCOHOLS BY K2FeO4-Al2O3-CuSO4*5H2O
Kim, Kwan Soo,Song, Yang Heon,Lee, Nam Ho,Hahn, Chi Sun
, p. 2875 - 2878 (2007/10/02)
A solid mixture of K2FeO4, Al2O3 and CuSO4*5H2O efficiently oxidized allylic, benzylic, and saturated secondary alcohols to the corresponding aldehydes or ketones but did not oxidize saturated primary alcohols.
