124957-63-7

Basic information

• Product Name: 2-Propenoic acid, 2-(azidomethyl)-3-phenyl-, methyl ester, (2E)-
• CAS NO: 124957-63-7
• Molecular Formula: C11H11N3O2
• Molecular Weight: 217.227
• Mol File: 124957-63-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-(azidomethyl)-3-phenyl-, methyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-(azidomethyl)-3-phenyl-, methyl ester, (2E)-(124957-63-7)
• EPA Substance Registry System: 2-Propenoic acid, 2-(azidomethyl)-3-phenyl-, methyl ester, (2E)-(124957-63-7)

Safety Data

• Hazardous Substances Data: 124957-63-7(Hazardous Substances Data)

Usage

Classification

Azido compound

Use

Building block in organic synthesis, preparation of various organic compounds, potential applications in photochemistry and materials science

Hazards

Potential hazards associated with azide functional group

Unique properties

Unique structure and reactivity in the field of organic chemistry

Upstream product

• 100-52-7 benzaldehyde 
• 18020-59-2 methyl 3-hydroxy-2-methylidene-3-phenylpropionate 
• 103669-71-2 (Z)-methyl 2-(bromomethyl)-3-phenylacrylate 
• 124957-36-4 Methyl 3-acetoxy-2-methylene-3-phenylpropanoate 

Downstream Products

• 124957-67-1 2-aminomethyl-3-phenylacrylic acid methyl ester 
• 889855-43-0 methyl (E)-2-[(tert-butoxycarbonylamino)methyl]-3-phenylacrylate 
• 1192824-58-0 C₁₇H₁₅N₅O₂ 
• 1192824-53-5 C₁₈H₁₆N₄O₂ 

Relevant articles and documents

Fast and efficient preparation of Baylis-Hillman-derived (E)-allylic azides and related compounds in aqueous medium

A practical access to alkyl- and aryl-substituted (E)-2-(azidomethyl)alkenoates and related azido compounds from the corresponding allylic bromides in aqueous acetone is described. An alternative method to obtain the starting bromides based on heterogeneo

Synthesis of aryl-(E)-2-(azidomethyl)alkenoate and aryl-(Z)-2-(azidomethyl)acrylonitrile from aryl aldehydes and activated alkenes via one-pot way

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N-bromosuccinimide-mediated radical cyclization of 3-arylallyl azides: Synthesis of 3-substituted quinolines

Visible light irradiation of N-bromosuccinimide serves as an effective means to convert methyl 2-(azidomethyl)-3-arylpropenoates and 2-(azidomethyl)-3-arylacrylonitriles to the corresponding iminyl radicals via ?±-hydrogen abstraction and subsequent extrusion of dinitrogen. Thus formed iminyl radicals then undergo intramolecular ortho attack on the aryl ring, affording methyl quin-oline-3-carboxylates and quinoline-3-carbonitriles respectively.