125073-32-7Relevant academic research and scientific papers
Uncatalyzed and chorismate mutase catalyzed claisen rearrangements of 5,6-dihydrochorismate and 6-Oxa-5,6-dihydrochorismate
Delany III, John J.,Padykula, Robert E.,Berchtold, Glenn A.
, p. 1394 - 1397 (1992)
The synthesis of 6-oxa-5,6-dihydrochorismic acid (4) from D-xylose is described. The half-lives for the uncatalyzed Claisen rearrangements of 5,6-dihydrochorismic acid (3) and 4 in D2O at 30 °C were 49000 and 1200 h, respectively, compared to a
