Uncatalyzed and chorismate mutase catalyzed claisen rearrangements of 5,6-dihydrochorismate and 6-Oxa-5,6-dihydrochorismate

DOI: 10.1021/ja00030a039

Source and publish data:

Journal of the American Chemical Society p. 1394 - 1397 (1992)

Update date:2022-08-05

Topics: Experimental terms Uncatalyzed Chorismate mutase Claisen rearrangements

Authors:

Delany III, John J.

Padykula, Robert E.

Berchtold, Glenn A.

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Article abstract of DOI:10.1021/ja00030a039

The synthesis of 6-oxa-5,6-dihydrochorismic acid (4) from D-xylose is described. The half-lives for the uncatalyzed Claisen rearrangements of 5,6-dihydrochorismic acid (3) and 4 in D₂O at 30 °C were 49000 and 1200 h, respectively, compared to a

Full text of DOI:10.1021/ja00030a039

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