Journal of the American Chemical Society p. 1394 - 1397 (1992)
Update date:2022-08-05
Topics: Experimental terms Uncatalyzed Chorismate mutase Claisen rearrangements
Delany III, John J.
Padykula, Robert E.
Berchtold, Glenn A.
The synthesis of 6-oxa-5,6-dihydrochorismic acid (4) from D-xylose is described. The half-lives for the uncatalyzed Claisen rearrangements of 5,6-dihydrochorismic acid (3) and 4 in D2O at 30 °C were 49000 and 1200 h, respectively, compared to a
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