125074-84-2Relevant academic research and scientific papers
Stereoselective hydride reductions of chiral 2-p-tolylsulfinylcycloalkanones
Bueno, Ana B.,Carmen Carreno,Garcia Ruano, Jose L.,Pena, Begona,Rubio, Almudena,Hoyos, Miguel A.
, p. 9355 - 9364 (1994)
The highly stereoselective hydride reductions of chiral 2-p-tolylsulfinyl-cyclopentanones and- cycloheptanones are described. With DIBAL (electrophilic hydride) the configuration induced at C-1 is controlled by the sulfinyl group (1,3-asymmetric induction
Stereoselective Reductions of 2-Keto Sulfoxides with Hydrides
Carreno, M. Carmen,Ruano, Jose L. Garcia,Martin, Ana M.,Pedregal, Concepcion,Rodriguez, Jesus H.,et al.
, p. 2120 - 2128 (2007/10/02)
The results of reductions of some acyclic 2-keto sulfoxides (ArC(O)CH2S(O)R; Ar=Ph, 2-Py, 4-Py, and R=Me, p-Tol) and flexible and rigid 2-sulfinylcyclohexanone diastereomers with various metal hydrides are reported.The configurational assignment and confo
