Tetrahedron p. 9355 - 9364 (1994)
Update date:2022-08-02
Topics:
Bueno, Ana B.
Carmen Carreno
Garcia Ruano, Jose L.
Pena, Begona
Rubio, Almudena
Hoyos, Miguel A.
The highly stereoselective hydride reductions of chiral 2-p-tolylsulfinyl-cyclopentanones and- cycloheptanones are described. With DIBAL (electrophilic hydride) the configuration induced at C-1 is controlled by the sulfinyl group (1,3-asymmetric induction
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