125085-11-2

Basic information

• Product Name: phenyl 4-O-(2-O-acetyl-3,4-di-O-benzyl-6-deoxy-β-D-glucopyranosyl)-2,3-di-O-benzyl-6-deoxy-1-thio-β-D-glucopyranoside
• Synonyms: phenyl 4-O-(2-O-acetyl-3,4-di-O-benzyl-6-deoxy-β-D-glucopyranosyl)-2,3-di-O-benzyl-6-deoxy-1-thio-β-D-glucopyranoside
• CAS NO: 125085-11-2
• Molecular Weight: 805.001
• Mol File: 125085-11-2.mol

Chemical Properties

• CAS DataBase Reference: phenyl 4-O-(2-O-acetyl-3,4-di-O-benzyl-6-deoxy-β-D-glucopyranosyl)-2,3-di-O-benzyl-6-deoxy-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 4-O-(2-O-acetyl-3,4-di-O-benzyl-6-deoxy-β-D-glucopyranosyl)-2,3-di-O-benzyl-6-deoxy-1-thio-β-D-glucopyranoside(125085-11-2)
• EPA Substance Registry System: phenyl 4-O-(2-O-acetyl-3,4-di-O-benzyl-6-deoxy-β-D-glucopyranosyl)-2,3-di-O-benzyl-6-deoxy-1-thio-β-D-glucopyranoside(125085-11-2)

Safety Data

• Hazardous Substances Data: 125085-11-2(Hazardous Substances Data)

Upstream product

• 24877-07-4 2,3,4-tri-O-acetyl-6-deoxy-α-D-glucopyranosyl bromide 
• 87470-70-0 2,3-di-O-benzyl-4,6-O-benzylidene-1-thiophenyl-β-D-glucopyranoside 
• 125278-25-3 3,4-di-O-benzyl-6-deoxy-1,2-O-(1-methoxyethylidene)-α-D-glucopyranose 
• 125085-03-2 phenyl 2,3-di-O-benzyl-6-deoxy-1-thio-β-D-glucopyranoside 
• 125135-31-1 1,2-di-O-acetyl-3,4-di-O-benzyl-6-deoxy-β-D-glucopyranose 

Downstream Products

• 125209-26-9 phenyl 2,3-di-O-benzyl-6-deoxy-4-O-(3,4-di-O-benzyl-6-deoxy-2-O-(methylthio)thiocarbonyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside 
• 124477-14-1 phenyl 2,3-di-O-benzyl-6-deoxy-4-O-(3,4-di-O-benzyl-2,6-dideoxy-β-D-arabino-hexapyranosyl)-1-thio-β-D-glucopyranoside 

Relevant articles and documents

AN EASY SYNTHESIS OF 2'-DEOXY-β-DISACCHARIDES

1,2-Di-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranose and analogs are excellent β-glycosyl donors in the presence of trimethylsilyltriflate.The resulting disaccharides are easily converted into the corresponding 2'-deoxy-β-disaccharides, opening a practical route to this important class of natural molecules.

tHE SYNTHESIS OF 2'-DEOXY-β-DISACCHARIDES: NOVEL APPROACHES

Benzylated 1,2-orthoacetates were converted by dry acetic acid into 1,2-trans-diacetates which behaved as excellent β-glycosyl donors with various non-acylated glycosyl acceptors in the presence of trimethylsilyl triflate.Deacetylation, followed by xantha