124477-14-1Relevant articles and documents
AN EASY SYNTHESIS OF 2'-DEOXY-β-DISACCHARIDES
Trumtel, Michel,Veyrieres, Alain,Sinay, Pierre
, p. 2529 - 2532 (2007/10/02)
1,2-Di-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranose and analogs are excellent β-glycosyl donors in the presence of trimethylsilyltriflate.The resulting disaccharides are easily converted into the corresponding 2'-deoxy-β-disaccharides, opening a practical route to this important class of natural molecules.
tHE SYNTHESIS OF 2'-DEOXY-β-DISACCHARIDES: NOVEL APPROACHES
Trumtel, Michel,Tavecchia, Paolo,Veyrieres, Alain,Sinay, Pierre
, p. 29 - 52 (2007/10/02)
Benzylated 1,2-orthoacetates were converted by dry acetic acid into 1,2-trans-diacetates which behaved as excellent β-glycosyl donors with various non-acylated glycosyl acceptors in the presence of trimethylsilyl triflate.Deacetylation, followed by xantha