125101-83-9Relevant academic research and scientific papers
An expeditious aqueous Suzuki-Miyaura method for the arylation of bromophenols
Freundlich, Joel S.,Landis, Howard E.
, p. 4275 - 4279 (2006)
The development of a novel Suzuki-Miyaura method has been achieved to allow the efficient arylation of bromophenols. A range of functionality is tolerated with regard to the boronic acid coupling partner and the reaction exhibits complete chemoselectivity for the Caryl-Br bond versus the Caryl-Cl bond in the aryl halide input. The experimental protocol features a short reaction time of 15 min, utilizes inexpensive Pd/C as a catalyst, and is conducted with water as the solvent.
WB4101-related compounds: New, subtype-selective α1- adrenoreceptor antagonists (or inverse agonists?)
Pallavicini, Marco,Budriesi, Roberta,Fumagalli, Laura,Ioan, Pierfranco,Chiarini, Alberto,Bolchi, Cristiano,Ugenti, Maria Paola,Colleoni, Simona,Gobbi, Marco,Valoti, Ermanno
, p. 7140 - 7149 (2007/10/03)
Our previous structure-affinity relationship study had considered the enantiomers of the naphthodioxane, tetrahydronaphthodioxane, and 2-methoxy-1-naphthoxy analogues (compounds 1, 3, and 2, respectively) of 2-(2,6-dimethoxyphenoxyethylaminomethyl)-1,4-be
A new entry to the synthesis of 1,2-benzenediol congeners
Ozaki,Oshio,Ohsuga,Kaburagi,Sung,Kim
, p. 1132 - 1136 (2007/10/02)
1,2-Benzenediols were synthesized via 1,1-bis(ethylthio)-3-cyclohexen-2-one derivatives, which were prepared by condensation of 1,1-bis(ethylthio)-2-propanone with Mannich bases. Regioselective preparation of their monoethers was also achieved.
A NEW ENTRY TO 1,2-BENZENEDIOL CONGENERS
Ozaki, Yutaka,Oshio, Ikumi,Kim, Sang-Won
, p. 1434 - 1436 (2007/10/02)
1,2-Benzenediols and their monoethers were efficiently prepared from α,α-bis(ethylthio)cyclohexenones which were constructed by the C3+C3 annulation of 1,1-bis(ethylthio)propan-2-one and the Mannich bases. KEYWORDS 1,2-benzenediol; aromatic synthesis; annulation; aromatic compound; acetal
