125151-61-3

Upstream product

• 123883-51-2 1-bromo-4-dodecyloxybenzene 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 540-38-5 p-Iodophenol 
• 143-15-7 1-dodecylbromide 
• 116223-59-7 1-(dodecyloxy)-4-iodobenzene 

Downstream Products

• 128345-29-9 4-(4-Dodecyloxy-phenylethynyl)-benzoic acid (S)-2-methyl-butyl ester 
• 182573-01-9 methyl 6'-(4-dodecyloxyphenylethynyl)-2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate 
• 121051-42-1 1-(dodecyloxy)-4-ethynylbenzene 

Relevant academic research and scientific papers

Thermal and nonlinear optical studies of newly synthesized EDOT based bent-core and hockey-stick like liquid crystals

Novel EDOT based bent-core and hockey-stick shaped mesogens bearing terminal alkyl chains and alkoxy terminal chains, respectively, have been designed and synthesized via the Sonogashira coupling reaction. Molecular structures of these new compounds were

Dithia-s-indacene derivative

A 1,5-dithia-s-indacene or 1,7-dithia-s-indacene derivative represented by general formula (1): wherein R1 and R2 each independently represents a hydrogen atom, an alkyl group or an alkoxy group; R3-R12 each ind

Synthesis and mesomorphic properties of some fluorinated benzoate liquid crystals

Three series of [4-(4′-n-alkyloxyphenyl)acetylenyl]-2,6- difluorophenyl fluorinated benezoates and one series of fluorinated benzoates with 2,3,5,6-tetrafluorophenylene group and semi-perfluorocarbon chain have been synthesized. Their phase transition temperatures have been measured by texture observation in a polarizing microscope and confirmed by DSC. For the series without fluorocarbon chains, increasing the quantity of fluorosubstituents on the terminal phenyl groups decreased nematic stability (TN-I), but the breadth of the SmA phase range was increased. Lateral fluorosubstitution in the central group lowered the nematic stability (TN-I) and decreased the breadth of the SmA phase range. The series with semiperfluorocarbon chains were more likely to form SmA phases than the series with hydrogencarbon chains, and with the increasing of fluorosubstituents quantity on the terminal phenyl groups nematic and SmA stability (TN-I and TsmA-N) were both decreased.

Synthesis and mesomorphic properties of some fluoro-substituted benzoates

Several series of fluoro-substituted benzoate liquid crystals have been synthesized. The results showed that the SmA phase is enhanced with the increasing of the degree of fluoro-substitution on the para- and meta-position of the terminal phenyl groups. And the molecules which have same molecular structural formula show nearly the same melting points. It is also discussed about the effect of the ester bond's direction on the mesomorphic properties.

Synthesis of 1,1'-Binaphthalene-2,2'-Diol Derivatives Containing Mesogenic Structural Fragments

Methyl 2,2'-dihydroxy-6'-iodo-1,1'-binaphthalene-3-carboxylate has been synthesized. A procedure has been developed for selective acetylation of the hydroxy group in position 2' of this compound, as well as for acylation of methyl 2,2'-dihydroxy-6'-iodo-1