125152-25-2Relevant academic research and scientific papers
Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions
Ilovaisky,Merkulova,Ogibin,Nikishin
, p. 1585 - 1592 (2007/10/03)
Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35-85% yields), dinitro compounds (15-51%), nitronitriles (6-27%), and nitrosulfones (50-70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.
Base-Catalyzed Reaction of α-Nitronitriles with Alcohols
Matacz, Zygmunt,Piotrowska, Hanna,Poplawska, Magdalena
, p. 139 - 146 (2007/10/02)
α-Nitronitriles react with primary and secondary alcohols in the presence of bases to give α-nitroimidates in high yields.When equimolar amount of an alkoxide is used the product formed depends on the order of the alcohol applied.
