125155-22-8Relevant academic research and scientific papers
Arylation of allylphosphonates and application to the preparation of phosphonomethyl-coumarin, -quinolinone and -benzoxepinone skeletons
Abdelli, Abderrahmen,Gaucher, Anne,Efrit, Mohamed Lotfi,M'rabet, Hedi,Prim, Damien
, p. 1679 - 1681 (2015)
An efficient and selective synthesis of Z-(het)arylallylphosphonates is described. The versatile Pd-assisted process also allowed polyarylation sequences leading to star-shaped and binaphthyl derivatives. The methodology could be extended to the preparati
Simple and advantageneous stereoselective synthesis of (Z)-allyl phosphonates starting from Baylis-Hillman adducts
Das, Biswanath,Bhunia, Nisith,Damodar, Kongara
experimental part, p. 2479 - 2489 (2012/07/28)
(Chemical Equation Presented) Baylis-Hillman adducts 3-hydroxyl-2-methylene alkanoates have been converted in one pot into the corresponding (Z)-allyl phosphonates by treatment with FeCl3 and trialkyl phosphites in toluene under reflux. The pro
A Convenient Horner-Emmons Approach to the Synthesis of Substituted Ethyl 1,3-Butadiene-2-carboxylates, and Related Compounds
Janecki, Tomasz,Bodalski, Ryszard
, p. 506 - 510 (2007/10/02)
The Horner-Emmons reaction of the allylphosphonates 3 with aldehydes gives substituted 1,3-butadiene-2-carboxylates 12 in satisfactory yields.By suitable modification of reactants a variety of 3-alkenyl-2(5H)-furanones 13 and 3-alkenylcoumarins 14 are pre
