334024-11-2Relevant academic research and scientific papers
Cobalt-catalyzed regio- and stereoselective intermolecular enyne coupling: An efficient route to 1,3-diene derivatives
Mannathan, Subramaniyan,Cheng, Chien-Hong
supporting information; experimental part, p. 1923 - 1925 (2010/06/20)
The reaction of alkynes with vinyl arenes or vinyl trimethyl silane in the presence of a cobalt(II) complex, Zn and ZnI2 in CH 2Cl2 at rt to 50 °C provides 1,3-dienes in good to excellent yields. The Royal Society of Chemistry 2010.
A new manifold for the Morita reaction: Diene synthesis from simple aldehydes and acrylates/acrylonitrile mediated by phosphines
Palmelund, Anders,Myers, Eddie L.,Tai, Lik Ren,Tisserand, Steve,Butts, Craig P.,Aggarwal, Varinder K.
, p. 4128 - 4130 (2008/09/16)
Dienes have been formed with good stereoselectivity and in good yield from simple aldehydes and acrylates/acrylonitrile in the presence of a phosphine and a Lewis acid through a modification of the Morita reaction. The Royal Society of Chemistry.
A Convenient Horner-Emmons Approach to the Synthesis of Substituted Ethyl 1,3-Butadiene-2-carboxylates, and Related Compounds
Janecki, Tomasz,Bodalski, Ryszard
, p. 506 - 510 (2007/10/02)
The Horner-Emmons reaction of the allylphosphonates 3 with aldehydes gives substituted 1,3-butadiene-2-carboxylates 12 in satisfactory yields.By suitable modification of reactants a variety of 3-alkenyl-2(5H)-furanones 13 and 3-alkenylcoumarins 14 are pre
