125198-07-4Relevant articles and documents
Preparation of 2,3,4,5-tetrahydropyridines from 5-alkynylamines under the catalytic action of gold(III) salts
Fukuda,Utimoto
, p. 975 - 978 (1991)
Intramolecular addition of amine to carbon-carbon triple bonds in 5-alkynylamines produces 2,3,4,5-tetrahydropyridines under the catalytic action of an aurate salt. Some venom components of various ant species are synthesized by the application of this re
Palladium-Catalyzed Intramolecular Addition of Amines to Acetylenes. Synthesis of Cyclic Imines
Fukuda, Yukitoshi,Matsubara, Seijiro,Utimoto, Kiitiro
, p. 5812 - 5816 (2007/10/02)
Intramolecular aminopalladation of alkynylamines gave intermediary alkenylpalladium compounds that hydrolyzed and isomerized to thermodynamically stable cyclic imines.Treatment of 3-alkynylamines with a catalytic amount of PdCl2(MeCN)2 gave exclusively 1-