1252017-06-3Relevant academic research and scientific papers
Remarkable levels of enantioswitching in catalytic asymmetric hydroboration
Smith, Sean M.,Takacs, James M.
supporting information; experimental part, p. 4612 - 4615 (2010/12/19)
TADDOL-derived phosphites and phosphoramidites are effective ligands for rhodium-catalyzed asymmetric hydroborations of β,γ-unsaturated amides, achieving up to 99% ee. However, the sense of stereoinduction, R or S, is surprisingly dependent on rather subt
