1252259-79-2Relevant academic research and scientific papers
Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds
Ureshino, Tomonari,Yoshida, Takuya,Kuninobu, Yoichiro,Takai, Kazuhiko
supporting information; experimental part, p. 14324 - 14326 (2010/12/19)
The rhodium-catalyzed synthesis of silafluorenes from biphenylhydrosilanes is described. This highly efficient reaction proceeds via both Si-H and C-H bond activation, producing only H2 as a side product. Using this method, a ladder-type bis-silicon-bridged p-terphenyl could also be synthesized.
