125246-81-3Relevant academic research and scientific papers
Functionally Substituted Organic Peroxides. XIX. Kinetics of the Reaction of Poly- and Perfluorinated Carbonyl Compounds with tert-Butyl Hydroperoxide
Chapurkin
, p. 36 - 40 (2007/10/03)
The kinetics of noncatalytic reaction of fluorinated aliphatic and aromatic aldehydes, alkyl, cycloalkyl, and aryl ketones, and β-ketoesters with tert-butyl hydroperoxide were studied by IR spectroscopy.
FUNCTIONAL ORGANIC PEROXIDES. XVIII. STRUCTURAL CHARACTERISTICS OF THE PEROXIDES OF PERFLUOROCYCLOHEXANONE AND PERFLUOROCYCLOPENTANONE
Rakhimov, A. I.,Chapurkin, V. V.,Volynskaya, E. M.,Morozova, N. K.,Litinskii, A. O.
, p. 638 - 642 (2007/10/02)
The structural characteristics of the peroxides of perfluorocyclohexanone and perfluorocyclopentanone were studied by IR spectroscopy, 19F NMR spectroscopy, and quantum-chemical calculations.It was shown that the peroxide group is in the equatorial position.The introduction of the fluorine atoms promotes opening of the ring.
