1252576-01-4Relevant academic research and scientific papers
Enantioselective total synthesis of (-)-neovibsanin G and (-)-14-epi-neovibsanin G
Mak, Jeffrey Y. W.,Williams, Craig M.
, p. 287 - 289 (2012)
The first total synthesis of vibsane-type diterpenoids neovibsanin G and 14-epi-neovibsanin G has been achieved. Key to this endeavour was a late stage EtAlCl2 mediated skeletal rich cascade leading to the bicyclo[3.3.1]nonane core in one step.
Total synthesis of (-)-neovibsanin G and (-)-14-epi-neovibsanin G: Towards the synthesis of 15-O-methylneovibsanin F and 14-epi-15-O-methylneovibsanin F
Mak, Jeffrey Y. W.,Williams, Craig M.
, p. 2001 - 2012 (2012)
The total synthesis of (-)-neovibsanin G and (-)-14-epi-neovibsanin G has been accomplished, establishing the absolute configurations of these caged diterpenes as 11S, and confirming Fukuyama's postulated biosynthesis of the neovibsanins. Synthetic studie
