125263-30-1Relevant articles and documents
Synthesis and crystal structure of cis-1-benzylidene-1,2,3,4-tetrahydronaphthalene, containing an unexpected conformation of the cyclohexylidene ring
Bukowska-Strzyzewska, M.,Skoweranda, J.,Maniukiewicz, W.,Strzyzewski, W.
, p. 713 - 720 (1988)
Two isomers of 1-benzylidene-1,2,3,4-tetrahydronaphthalene have been synthesized by the Wittig reaction, and the crystal structure of the cis-isomer has been solved .The compound C17H16 crystallizes in the monoclinic space group P21/n with a = 9.796(2), b = 5.490(5), c = 23.215(3) Angstroem, β = 95.11(2) deg, and Z = 4.The structure was determined by direct methods, and refined by full-matrix least squares to R = 0.047 for 1104 reflections.The cyclohexylidene ring has the unusual envelope Cs2,10 conformation.
The photochemical rearrangement of 1,2-dihydronaphthalenes into 1,4-dihydronaphthalenes induced by amines
Cuppen, Th. J. H. M.,Berendsen, N.,Laarhoven, W. H.
, p. 168 - 171 (2007/10/02)
The synthetic usefulness of the deprotonation/protonation reaction of excited 1,2-dihydronaphthalenes into 1,4-dihydronaphthalenes induced by amines has been investigated using 13 different substituted 1,2-dihydronaphthalenes and related compounds.The yield of the rearrangement ranges from 5 to 96percent.The formation of side-products depends on the position of protons in the substrate, which can be abstracted by the amine, and on competitive photoreactions.