1253176-72-5Relevant academic research and scientific papers
Enantioselective Deuteration of β-Substituted α,β-Unsaturated Esters by Rhodium-1,2-Bis(2,5-diphenylphospholano)ethane
Lethu, Sébastien,Ano, Hikaru,Murata, Michio,Matsuoka, Shigeru
supporting information, p. 235 - 239 (2018/01/27)
We report an efficient method for the synthesis of a chiral C-CHD-CHD-C unit in threo form, which enables the asymmetric conformational analysis of straight alkyl chains. The vicinal dideuterated compound was constructed by enantioselective catalytic deut
Chiral cobalt-catalyzed enantioselective aerobic oxidation of α-hydroxy esters
Alamsetti, Santosh Kumar,Sekar, Govindasamy
supporting information; experimental part, p. 7235 - 7237 (2010/12/24)
A chiral cobalt-catalyzed enantioselective aerobic oxidative kinetic resolution of (±)-α-hydroxy esters, using molecular oxygen as a sole oxidant, is reported and a maximum of selectivity factor (s) 31.9 was achieved with >99% enantiomeric excess for unreacted α-hydroxy esters.
