1253389-89-7Relevant academic research and scientific papers
Gold(I)-catalyzed addition of diphenyl phosphate to alkynes: Isomerization of kinetic enol phosphates to the thermodynamically favored isomers
Lee, Phil Ho,Kim, Sundae,Park, Aeri,Chary, Bathoju Chandra,Kim, Sunggak
, p. 6806 - 6809 (2010)
(Chemical Equation Presented) Gold, gold, or... gold? It depends on the (gold) catalyst whether the product of thermodynamic or kinetic control is formed in an unprecedented hydrophosphoryloxylation approach to enol phosphates (see scheme). A third catalyst, [(C6F5) 3PAuOTf], was found to be exceedingly effective for the previously unknown isomerization of kinetic enol phosphates to the thermodynamically favored isomers. Tf=trifluoromethanesulfonyl; R=alkyl, cyclohexyl, Ph.
