125380-23-6Relevant academic research and scientific papers
Carbonyl Allylation by Vinyl Epoxides with SnCl2-TBA or SnCl2-LiI: Application to the Diastereoselective Synthesis of 1,3-Diols
Masuyama, Yoshiro,Nakata, Jun,Kurusu, Yasuhiko
, p. 2598 - 2599 (2007/10/02)
Vinyl epoxides reacted with aldehydes in the presence of stannous chloride-tetrabutylammonium bromide or stannous chloride-lithium iodide to produce 2-vinyl-1,3-diols regio- and diastereoselectively.
Stereoselective Construction of Quaternary Carbons by the Reaction of Aldehydes with Allylic Chromium Reagents Prepared from 1,3-Diene Monoepoxides and CrCl2
Fujimura, Osamu,Takai, Kazuhiko,Utimoto, Kiitiro
, p. 1705 - 1706 (2007/10/02)
A vinyl-substituted β-hydroxy carbanion synthon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of LiI.The reagent reacts with aldehydes to afford R*,R* adducts stereoselectivity.
