1254033-99-2Relevant academic research and scientific papers
Enantioselective hydrophosphination of enones with diphenylphosphine catalyzed by bis(imidazoline) NCN pincer palladium(II) complexes
Hao, Xin-Qi,Zhao, Yong-Wei,Yang, Jing-Jing,Niu, Jun-Long,Gong, Jun-Fang,Song, Mao-Ping
supporting information, p. 1801 - 1811 (2014/05/06)
A series of chiral NCN pincer Pd(II) complexes with 1,3-bis(2′- imidazolinyl)phenyl (Phebim) ligands were synthesized via the C-H activation or oxidative addition method. A dinuclear macrocyclic Pd(II) complex was also prepared by reaction of the Phebim-H
NHC-copper-catalyzed asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated ketones
Chen, Yun-Rong,Feng, Jian-Jun,Duan, Wei-Liang
, p. 595 - 597 (2014/01/23)
N-Heterocyclic carbene-copper-catalyzed asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated ketones was developed for the synthesis of chiral phosphorus derivatives in high yields with moderate enantioselectivity under mild conditions.
PCN pincer palladium(II) complex catalyzed enantioselective hydrophosphination of enones: Synthesis of pyridine-functionalized chiral phosphine oxides as NCsp3O pincer preligands
Hao, Xin-Qi,Huang, Juan-Juan,Wang, Tao,Lv, Jing,Gong, Jun-Fang,Song, Mao-Ping
, p. 9512 - 9530 (2015/01/09)
A series of chiral PCN pincer Pd(II) complexes VI- XIII with aryl-based aminophosphine-imidazoline or phosphinite-imidazoline ligands were synthesized and characterized. They were examined as enantioselective catalysts for the hydrophosphination of enones
Palladium(ii)-catalyzed asymmetric hydrophosphination of enones: Efficient access to chiral tertiary phosphines
Huang, Yinhua,Pullarkat, Sumod A.,Li, Yongxin,Leung, Pak-Hing
supporting information; experimental part, p. 6950 - 6952 (2010/11/04)
Chiral tertiary phosphines were synthesized by asymmetric hydrophosphination of aromatic enones catalyzed by an organopalladium complex with high yields and stereoselectivity. The procedure offers practical access to chiral tertiary phosphines.
