1254164-47-0Relevant articles and documents
Metal-Free, Initiator-Free Graphene Oxide-Catalyzed Trifluoromethylation of Arenes
Zhang, Jingyu,Yang, Yun,Fang, Jingxian,Deng, Guo-Jun,Gong, Hang
, p. 2524 - 2527 (2017)
The direct C?H trifluoromethylation of arenes catalyzed by graphene oxide (GO) under safe conditions is described. This strategy is metal-free, initiator-free, safe, and scalable. It employs a readily available CF3 source and the reaction can b
Metal-free direct C-H perfluoroalkylation of arenes and heteroarenes using a photoredox organocatalyst
Cui, Lei,Matusaki, Yoko,Tada, Norihiro,Miura, Tsuyoshi,Uno, Bunji,Itoh, Akichika
supporting information, p. 2203 - 2207 (2013/10/01)
We report the visible-light-induced trifluoromethylation of arenes and heteroarenes using sodium trifluoromethanesulfinate catalyzed by anthraquinone-2-carboxylic acid. This reaction is a metal-free trifluoromethylation of arenes and heteroarenes catalyzed by a photoredox organocatalyst. Perfluoroalkylated arenes were also produced using sodium perfluoroalkylsulfinates.