1254375-55-7Relevant academic research and scientific papers
Synthesis of the c1-c14 fragment of sarcoglaucol-16-one via z -selective ando-type horner-wadsworth-emmons olefination
Gastl, Christoph,Laschat, Sabine
, p. 2643 - 2651 (2010)
A synthetic strategy involving a Z-selective Horner-Wadsworth-Emmons olefination was developed for the preparation of the sarcoglaucolone precursor methyl (2Z,6E)-8-(methoxymethoxy)-6-methyl-2-[(3E)-4-methyl-5-oxopent-3-enyl]-9- [(trimethylsilyl)methyl]deca-2,6,9-trienoate. The target compound was isolated in a E/Z ratio of 17:83 Georg Thieme Verlag Stuttgart New York.
