125488-63-3

Basic information

• Product Name: (4R,5R)-1-C-(1,2-dimethyl-4-nitrocyclohex-1-en-5-yl)carbaldehyde
• Synonyms: (4R,5R)-1-C-(1,2-dimethyl-4-nitrocyclohex-1-en-5-yl)carbaldehyde
• CAS NO: 125488-63-3
• Molecular Weight: 183.207
• Mol File: 125488-63-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4R,5R)-1-C-(1,2-dimethyl-4-nitrocyclohex-1-en-5-yl)carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5R)-1-C-(1,2-dimethyl-4-nitrocyclohex-1-en-5-yl)carbaldehyde(125488-63-3)
• EPA Substance Registry System: (4R,5R)-1-C-(1,2-dimethyl-4-nitrocyclohex-1-en-5-yl)carbaldehyde(125488-63-3)

Safety Data

• Hazardous Substances Data: 125488-63-3(Hazardous Substances Data)

Upstream product

• 125488-62-2 (4R,5R)-1-C-(1,2-dimethyl-4-nitrocyclohex-1-en-5-yl)-D-manno-pentitol 
• 119479-73-1 (E)-3,4,5,6,7-penta-O-acetyl-1,2-dideoxy-1-C-nitro-D-manno-hept-1-enitol 
• 438625-50-4 1',2',3',4',5'-penta-O-acetyl-1'-C-[(4R,5R)-1,2-dimethyl-4-nitrocyclohex-1-en-5-yl]-D-manno-pentitol 
• 125488-62-2 (1R,2R,3R,4R)-1-((R)-3,4-Dimethyl-6-nitro-cyclohex-3-enyl)-pentane-1,2,3,4,5-pentaol 

Downstream Products

• 5973-71-7 3,4-dimethylbenzaldehyde 
• 82372-64-3 4,5-dimethylcyclohexa-1,4-diene-1-carbaldehyde 
• 478866-91-0 (4R,5R)-5-hydroxymethyl-1,2-dimethyl-4-nitrocyclohex-1-ene 

Relevant articles and documents

Reactions of hydroxylated sodium nitronates with acetic anhydride/pyridine

Reactions with Ac2O/Py of sodium nitronate salts derived from primary or secondary nitroalkanes bearing hydroxyl groups at γ or more remote positions have been studied. In all cases, the results could be explained through an acetic nitronic anhydride intermediate, whose evolution depends on conformational factors, and also on the type of the hydroxyl group.

ENANTIOSELECTIVE SYNTHESIS OF CYCLOHEXENE NITROALDEHYDES

An enantioselective synthesis of cyclohexene nitroaldehydes 2e-5e has been effected, via Diels-Alder reaction with sugar nitroolefins as chiral dienophiles.Absolute configuration of products has been determined by X-ray crystallographic analysis and chemi